Small-Angle Neutron Scattering Study of Solubilization of Tributyl Phosphate in Aqueous Solutions of L64 Pluronic Triblock Copolymers

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Small-angle neutron scattering study of solubilization of tributyl phosphate in aqueous solutions of L64 Pluronic triblock copolymers.

We have studied the solubilization behavior of tributylphosphate (TBP) in aqueous solutions of L64-Pluronics, using light and small angle neutron scattering (SANS). Varying the temperature and the oil content, the system presents a nontrivial phase behavior. In particular, at 308 K, a first solubilization followed by an emulsification failure and a resolubilization is found. We have measured th...

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Small angle neutron scattering

Small Angle Neutron Scattering (SANS) is a technique that enables to probe the 3-D structure of materials on a typical size range lying from ∼ 1 nm up to ∼ a few 100 nm, the obtained information being statistically averaged on a sample whose volume is ∼ 1 cm3. This very rich technique enables to make a full structural characterization of a given object of nanometric dimensions (radius of gyrati...

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ژورنال

عنوان ژورنال: Langmuir

سال: 2010

ISSN: 0743-7463,1520-5827

DOI: 10.1021/la1021164